Thomas Groy

PSC -C7A
PHYSICAL SCIENCE CENTER
TEMPE
Associate Research Professional
Academic Professional
TEMPE Campus
Mailcode
1704

Biography

Thomas L. Groy inherited the position of staff crystallographer in the Department of Chemistry (now School of Molecular Science) from Robert Von Dreele in the spring of 1986, when Bob was given the opportunity to become a prinicipal investigator at LANSCE in the Los Alamos National Laboratory.  After developing skills in the structure solution of single crystal diffraction data, Thomas was fortunate to collaborate with a new faculty hire, Omar M. Yaghi, who would become a world leader in the newly emerging field of metal-organic framework solids (MOFs).  Many of the highly recognized early structures in this area were solved in the crystallography labs by Thomas, and the resulting publications have become some of the most frequently cited in the scientific literature.  Due to the nature of his position, Thomas has been involved with researchers covering a large range of studies, including Chemistry, Engineering, Biology, Physics, Geology, and Anthropolgy.  The development of specialized experiments and the publications resulting from these interactions has enabled Thomas to become a well recognized contributor to all these areas.

 

Education

  • Ph.D. Physical Chemistry, Department of Chemistry and Biochemistry, Arizona State University, 1982
  • B.Sc. (Summa Cum Laude), Adams State University, 1976

Publications

 

Thomas L. Groy

Citations: 7312

h-index: 29

i10-index: 58

g-index: 85

 

1. "Controlling proton-coupled electron transfer in bioinspired artificial photosynthetic relays", Odella, Emmanuel; Mora, S. Jimena; Wadsworth, Brian L.; Huynh, Mioy T.; Goings, Joshua J.; Liddell, Paul A.; Groy, Thomas L.; Gervaldo, Miguel; Sereno, Leonides E.; Gust, Devens; et al, Journal of the American Chemical Society (2018), 140(45), 15450-15460.

 

2. "A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight", Mukhopadhyay, Tufan K.; Flores, Marco; Groy, Thomas L.; Trovitch, Ryan J., Chemical Science (2018), 9(39), 7673-7680.

 

3. "Ge0.57Ti0.43O2: a new high-pressure material with rutile-type crystal structure", Stoyanov, Emil; Leinenweber, Kurt; Groy, Thomas L.; Malik, Abds-Sami, Acta Crystallographica, Section E: Crystallographic Communications (2018), 74(7), 1010-1012.

 

4. "Carbonyl and ester C-O bond hydrosilylation using κ4-diimine nickel catalysts", Rock, Christopher L.; Groy, Thomas L.; Trovitch, Ryan J., Dalton Transactions (2018), 47(26), 8807-8816.

 

5. "Isolation of Mn(I) Compounds Featuring a Reduced Bis(imino)pyridine Chelate and Their Relevance to Electrocatalytic Hydrogen Production", Mukhopadhyay, Tufan K.; MacLean, Nicholas L.; Flores, Marco; Groy, Thomas L.; Trovitch, Ryan J., Inorganic Chemistry (2018), 57(10), 6065-6075.

 

6. "Hydrosilylation of Aldehydes and Formates Using a Dimeric Manganese Precatalyst", Mukhopadhyay, Tufan K.; Ghosh, Chandrani; Flores, Marco; Groy, Thomas L.; Trovitch, Ryan J., Organometallics (2017), 36(18), 3477-3483.

 

8. "Front Cover: Synthesis and Electrocatalytic Activity of [FeFe]-Hydrogenase Model Complexes with Non-Innocent Chelating Nitrogen-Donor Ligands (Eur. J. Inorg. Chem. /2017)", Roy, Souvik; Laureanti, Joseph A.; Groy, Thomas L.; Jones, Anne K., European Journal of Inorganic Chemistry (2017), 2017(23), 2940.

 

9. "Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst", Ben-Daat, Hagit; Rock, Christopher L.; Flores, Marco; Groy, Thomas L.; Bowman, Amanda C.; Trovitch, Ryan J., Chemical Communications (Cambridge, United Kingdom) (2017), 53(53), 7333-7336.

 

10. "Water-bearing, high-pressure Ca-silicates", Nemeth, Peter; Leinenweber, Kurt; Ohfuji, Hiroaki; Groy, Thomas; Domanik, Kenneth J.; Kovacs, Istvan J.; Kovacs, Judit S.; Buseck, Peter R., Earth and Planetary Science Letters (2017), 469, 148-155.

 

11. "Synthesis and Electrocatalytic Activity of [FeFe]-Hydrogenase Model Complexes with Non-Innocent Chelating Nitrogen-Donor Ligands", Roy, Souvik; Laureanti, Joseph A.; Groy, Thomas L.; Jones, Anne K., European Journal of Inorganic Chemistry (2017), 2017(23), 2942-2950.

 

12. "Mechanistic Investigation of Bis(imino)pyridine Manganese Catalyzed Carbonyl and Carboxylate Hydrosilylation", Mukhopadhyay, Tufan K.; Rock, Christopher L.; Hong, Mannkyu; Ashley, Daniel C.; Groy, Thomas L.; Baik, Mu-Hyun; Trovitch, Ryan J., Journal of the American Chemical Society (2017), 139(13), 4901-4915.

 

13. "Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst", Pal, Raja; Laureanti, Joseph A.; Groy, Thomas L.; Jones, Anne K.; Trovitch, Ryan J., Chemical Communications (Cambridge, United Kingdom) (2016), 52(77), 11555-11558.

 

14. "Reactivity of (Triphos)FeBr2(CO) towards sodium borohydrides", Mukhopadhyay, Tufan K.; Groy, Thomas L.; Smythe, Nathan C.; Gordon, John C.; Trovitch, Ryan J., Journal of Coordination Chemistry (2016), 69(11-13), 2038-2046.

 

15. "Isolation of a bis(imino)pyridine molybdenum(I) iodide complex through controlled reduction and interconversion of its reaction products", Pal, Raja; Cherry, Brian R.; Flores, Marco; Groy, Thomas L.; Trovitch, Ryan J., Dalton Transactions (2016), 45(24), 10024-10033.

 

16. "C-H and C-P activation by a redox non-innocent ligand supported iron dinitrogen complex", Ghosh, Chandrani; Groy, Thomas L.; Bowman, Amanda C.; Trovitch, Ryan J., Abstracts of Papers, 251st ACS National Meeting & Exposition, San Diego, CA, United States, March 13-17, 2016 (2016), INOR-956.

 

17. "Introducing a κ4-diazadiene Co(I) hydride catalyst for alkyne hydroboration", Ben-Daat, Hagit; Groy, Thomas L.; Trovitch, Ryan J., Abstracts of Papers, 251st ACS National Meeting & Exposition, San Diego, CA, United States, March 13-17, 2016 (2016), INOR-348.

 

18. "Redox non-innocent ligand supported manganese complexes for solar-fuel generation", Mukhopadhyay, Tufan K.; Groy, Thomas L.; Trovitch, Ryan J., Abstracts of Papers, 251st ACS National Meeting & Exposition, San Diego, CA, United States, March 13-17, 2016 (2016), INOR-1306.

 

19. "Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex", Ghosh, Chandrani; Groy, Thomas L.; Bowman, Amanda C.; Trovitch, Ryan J., Chemical Communications (Cambridge, United Kingdom) (2016), 52(24), 4553-4556.

 

20. "Molybdenum (I) oxidation state: Preparation, characterization, and reactivity of bis(imino)pyridine Mo complexes", Pal, Raja; Flores, Marco; Groy, Thomas; Trovitch, Ryan, Abstracts of Papers, 251st ACS National Meeting & Exposition, San Diego, CA, United States, March 13-17, 2016 (2016), INOR-229.

 

21. "A Pentacoordinate Mn(II) Precatalyst That Exhibits Notable Aldehyde and Ketone Hydrosilylation Turnover Frequencies", Ghosh, Chandrani; Mukhopadhyay, Tufan K.; Flores, Marco; Groy, Thomas L.; Trovitch, Ryan J., Inorganic Chemistry (2015), 54(21), 10398-10406.

 

22. "Conversion of carbon dioxide to methanol using a C-H activated bis(imino)pyridine molybdenum hydroboration catalyst", Pal, Raja; Groy, Thomas L.; Trovitch, Ryan J., Inorganic Chemistry (2015), 54(15), 7506-7515.

 

23. "Carbon Dioxide Promoted H+ Reduction Using a Bis(imino)pyridine Manganese Electrocatalyst", Mukhopadhyay, Tufan K.; MacLean, Nicholas L.; Gan, Lu; Ashley, Daniel C.; Groy, Thomas L.; Baik, Mu-Hyun; Jones, Anne K.; Trovitch, Ryan J., Inorganic Chemistry (2015), 54(9), 4475-4482.

 

24. "Substantial production of drosophilin A methyl ether (tetrachloro-1,4-dimethoxybenzene) by the lignicolous basidiomycete Phellinus badius in the heartwood of mesquite (Prosopis juliflora) trees", Garvie, Laurence A. J.; Wilkens, Barry; Groy, Thomas L.; Glaeser, Jessie A., Science of Nature (2015), 102(3-4), 1-8.

 

25. "Antineoplastic Agents. 599. Total Synthesis of Dolastatin 16", Pettit, George R.; Smith, Thomas H.; Arce, Pablo M.; Flahive, Erik J.; Anderson, Collin R.; Chapuis, Jean-Charles; Xu, Jun-Ping; Groy, Thomas L.; Belcher, Paul E.; MacDonald, Christian B., Journal of Natural Products (2015), 78(3), 476-485.

 

26. "A Nickel Phosphine Complex as a Fast and Efficient Hydrogen Production Catalyst", Gan, Lu; Groy, Thomas L.; Tarakeshwar, Pilarisetty; Mazinani, Shobeir K. S.; Shearer, Jason; Mujica, Vladimiro; Jones, Anne K., Journal of the American Chemical Society (2015), 137(3), 1109-1115.

 

27. "Preparation and Hydrosilylation Activity of a Molybdenum Carbonyl Complex That Features a Pentadentate Bis(imino)pyridine Ligand", Pal, Raja; Groy, Thomas L.; Bowman, Amanda C.; Trovitch, Ryan J., Inorganic Chemistry (2014), 53(17), 9357-9365.

 

28. "Catalytic Hydrogen Evolution by Fe(II) Carbonyls Featuring a Dithiolate and a Chelating Phosphine", Roy, Souvik; Mazinani, Shobeir K. S.; Groy, Thomas L.; Gan, Lu; Tarakeshwar, Pilarisetty; Mujica, Vladimiro; Jones, Anne K., Inorganic Chemistry (2014), 53(17), 8919-8929.

 

29. "Antineoplastic Agents. 595. Structural Modifications of Betulin and the X-ray Crystal Structure of an Unusual Betulin Amine Dimer", Pettit, George R.; Melody, Noeleen; Hempenstall, Frank; Chapuis, Jean-Charles; Groy, Thomas L.; Williams, Lee, Journal of Natural Products (2014), 77(4), 863-872.

 

30. "A bioinspired redox relay that mimics radical interactions of the Tyr-His pairs of photosystem II", Megiatto, Jackson D., Jr.; Mendez-Hernandez, Dalvin D.; Tejeda-Ferrari, Marely E.; Teillout, Anne-Lucie; Llansola-Portoles, Manuel J.; Kodis, Gerdenis; Poluektov, Oleg G.; Rajh, Tijana; Mujica, Vladimiro; Groy, Thomas L.; et al, Nature Chemistry (2014), 6(5), 423-428.

 

31. "A Highly Active Manganese Precatalyst for the Hydrosilylation of Ketones and Esters", Mukhopadhyay, Tufan K.; Flores, Marco; Groy, Thomas L.; Trovitch, Ryan J., Journal of the American Chemical Society (2014), 136(3), 882-885.

 

32. "Importance of co-donor field strength in the preparation of tetradentate α-diimine nickel hydrosilylation catalysts", Porter, Tyler M.; Hall, Gabriel B.; Groy, Thomas L.; Trovitch, Ryan J., Dalton Transactions (2013), 42(41), 14689-14692.

 

33. "Development of redox-active ligand supported manganese catalysts", Mukhopadhyay, Tufan K.; Groy, Thomas L.; Trovitch, Ryan J., Abstracts of Papers, 246th ACS National Meeting & Exposition, Indianapolis, IN, United States, September 8-12, 2013 (2013), INOR-619.

 

34. "Synthesis and characterization of formally zerovalent α-diimine supported nickel complexes", Porter, Tyler M.; Groy, Thomas L.; Trovitch, Ryan J., Abstracts of Papers, 246th ACS National Meeting & Exposition, Indianapolis, IN, United States, September 8-12, 2013 (2013), INOR-618.

 

35. "Rational Design of Rhodium Complexes Featuring κ4-N,N,N,N- and κ5-N,N,N,P,P-Bis(imino)pyridine Ligands", Ben-Daat, Hagit; Hall, Gabriel B.; Groy, Thomas L.; Trovitch, Ryan J., European Journal of Inorganic Chemistry (2013), 2013(25), 4430-4442.

 

36. "Artificial hydrogenases: Utilization of peptide and redox non-innocent ligands in [FeFe] and [NiFe] complexes", Roy, Souvik; Gan, Lu; Dutta, Arnab; Hamilton, G. A.; Groy, Thomas; Hartnett, Hilairy E.; Jones, Anne K., Abstracts of Papers, 245th ACS National Meeting & Exposition, New Orleans, LA, United States, April 7-11, 2013 (2013), ENFL-668.

 

37. "Artificial hydrogenases: utilization of peptide and redox non-innocent ligands in [FeFe] and [NiFe] complexes", Roy, Souvik; Gan, Lu; Dutta, Arnab; Hamilton, G. Alexander; Groy, Thomas L.; Hartnett, Hilairy E.; Jones, Anne K., Preprints - American Chemical Society, Division of Energy & Fuels (2013), 58(1), 480-481.

 

38. "Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2'-bipyridyl ligand", Roy, Souvik; Groy, Thomas L.; Jones, Anne K., Dalton Transactions (2013), 42(11), 3843-3853.

 

39. "Modeling, Synthesis and Biological Evaluation of Potential Retinoid X Receptor-Selective Agonists: Novel Halogenated Analogues of 4-[1-(3,5,5,8,8-Pentamethyl-5,6,7,8-tetrahydro-2-naphthyl)ethynyl]benzoic Acid (Bexarotene)", Furmick, Julie K.; Kaneko, Ichiro; Walsh, Angela N.; Yang, Joanna; Bhogal, Jaskaran S.; Gray, Geoffrey M.; Baso, Juan C.; Browder, Drew O.; Prentice, Jessica L. S.; Montano, Luis A.; et al, ChemMedChem (2012), 7(9), 1551-1566, S1551/1-S1551/76.

 

40. "Investigating Hydrogen-Bonded Phosphonic Acids with Proton Ultrafast MAS NMR and DFT Calculations", Blanchard, John W.; Groy, Thomas L.; Yarger, Jeffery L.; Holland, Gregory P., Journal of Physical Chemistry C (2012), 116(35), 18824-18830.

 

41. "Structure of a new form of silicon phosphate (SiP2O7) synthesized at high pressures and temperatures", Leinenweber, Kurt; Stearns, Linda A.; Nite, Jacob M.; Nemeth, Peter; Groy, Thomas L., Journal of Solid State Chemistry (2012), 190, 221-225.

 

43. "Molecular asymmetry in extraterrestrial organic chemistry: An analytical perspective", Pizzarello, Sandra; Groy, Thomas L., Geochimica et Cosmochimica Acta (2011), 75(2), 645-656.

 

44. "Facile Synthesis and Characterization of Phosphorescent Pt(N-C-N)X Complexes", Wang, Zixing; Turner, Eric; Mahoney, Vanessa; Madakuni, Sijesh; Groy, Thomas; Li, Jian, Inorganic Chemistry (2010), 49(24), 11276-11286.

 

45. "A new phase in the system lithium-aluminum: Characterization of orthorhombic Li2Al", Puhakainen, Kati; Bostroem, Magnus; Groy, Thomas L.; Haeussermann, Ulrich, Journal of Solid State Chemistry (2010), 183(11), 2528-2533.

 

46. "2-Fluoro-4-(methoxycarbonyl)benzoic acid", Wagner, Carl E.; Groy, Thomas L., Acta Crystallographica, Section E: Structure Reports Online (2010), 66(9), o2340.

 

47. "Methyl (Z)-2-chloro-3-(2-methoxycarbonylphenyl)prop-2-enoate", Fadgen, Casey J.; Groy, Thomas L.; Rose, Seth D., Acta Crystallographica, Section E: Structure Reports Online (2010), 66(2), o376, So376/1-So376/7.

 

48. "Growth and single-crystal refinement of phase-III potassium nitrate, KNO3", Freney, Evelyn J.; Garvie, Laurence A. J.; Groy, Thomas L.; Buseck, Peter R., Acta Crystallographica, Section B: Structural Science (2009), 65(6), 659-663.

 

49. "Modeling, Synthesis and Biological Evaluation of Potential Retinoid X Receptor (RXR) Selective Agonists: Novel Analogues of 4-[1-(3,5,5,8,8-Pentamethyl-5,6,7,8-tetrahydro-2-naphthyl)ethynyl]benzoic Acid (Bexarotene)", Wagner, Carl E.; Jurutka, Peter W.; Marshall, Pamela A.; Groy, Thomas L.; van der Vaart, Arjan; Ziller, Joseph W.; Furmick, Julie K.; Graeber, Mark E.; Matro, Erik; Miguel, Belinda V.; et al, Journal of Medicinal Chemistry (2009), 52(19), 5950-5966.

 

50. "Antineoplastic Agents. 579. Synthesis and Cancer Cell Growth Evaluation of E-Stilstatin 3: A Resveratrol Structural Modification", Pettit, George R.; Melody, Noeleen; Thornhill, Andrew; Knight, John C.; Groy, Thomas L.; Herald, Cherry L., Journal of Natural Products (2009), 72(9), 1637-1642.

 

51. "Synthesis and Fundamental Properties of Stable Ph3SnSiH3 and Ph3SnGeH3 Hydrides: Model Compounds for the Design of Si-Ge-Sn Photonic Alloys", Tice, Jesse B.; Chizmeshya, Andrew V. G.; Groy, Thomas L.; Kouvetakis, John, Inorganic Chemistry (2009), 48(13), 6314-6320.

 

52. "Zn5Sb4In2-δ - a Ternary Derivative of Thermoelectric Zinc Antimonides", Wu, Yang; Lidin, Sven; Groy, Thomas L.; Newman, N.; Haussermann, Ulrich, Inorganic Chemistry (2009), 48(13), 5996-6003.

 

53. "High-pressure modifications of CaZn2, SrZn2, SrAl2, and BaAl2: Implications for Laves phase structural trends", Kal, Subhadeep; Stoyanov, Emil; Belieres, Jean-Philippe; Groy, Thomas L.; Norrestam, Rolf; Haeussermann, Ulrich, Journal of Solid State Chemistry (2008), 181(11), 3016-3023.

 

54. "Synthesis and properties of N3 and CN delivery compounds and related precursors for nitride and ceramic fabrication", Tice, Jesse B.; Ritter, C. J.; Chizmeshya, A. V. G.; Forrest, Brandon; Torrison, Levi; Groy, T. L.; Kouvetakis, J., Applied Organometallic Chemistry (2008), 22(8), 451-459.

 

55. "Redetermination of tetrakis(trimethylstannyl)germane", Bauer, Matthew; Groy, Thomas L.; Kouvetakis, John, Acta Crystallographica, Section E: Structure Reports Online (2008), 64(1), m49, m49/1-m49/6.

 

56. "Tetrakis(N,N-diethylcarbamato)titanium(IV)", Straessler, Nicholas A.; Caudle, M. Tyler; Groy, Thomas L., Acta Crystallographica, Section E: Structure Reports Online (2008), 64(1), m48, m48/1-m48/9.

 

57. "Di-μ-chlorido-bis[dichlorido(N,N-diethylacetamidinato)(N,N-diethylacetamidine)titanium(IV)] acetonitrile disolvate", Straessler, Nicholas A.; Caudle, M. Tyler; Groy, Thomas L., Acta Crystallographica, Section E: Structure Reports Online (2008), 64(1), m20, m20/1-m20/8.

 

58. "Synthesis of Molecular Adducts of Beryllium, Boron, and Gallium Cyanides: Theoretical and Experimental Correlations between Solid-State and Molecular Analogues", Chizmeshya, A. V. G.; Ritter, C. J.; Groy, T. L.; Tice, J. B.; Kouvetakis, J., Chemistry of Materials (2007), 19(24), 5890-5901.

 

59. "μ-Oxido-bis[dichlorido(diethylamido-κN)(diethylamine-κN)titanium(IV)]", Straessler, Nicholas A.; Caudle, M. Tyler; Groy, Thomas L., Acta Crystallographica, Section E: Structure Reports Online (2007), 63(10), m2563, Sm2563/1-Sm2563/6.

 

60. "SrZn11: a new binary compound with the BaCd11 structure", Kal, Subhadeep; Stoyanov, Emil; Groy, Thomas L.; Haeussermann, Ulrich, Acta Crystallographica, Section C: Crystal Structure Communications (2007), 63(10), i96-i98.

 

61. "Di-μ-acetato-κ4O:O'-μ-oxido-κ2O:O-bis[(acetic acid-κO)bis(1H-imidazole-κN3)magnesium(II)]", Stadie, Nicholas P.; Sanchez-Smith, Rebeca; Groy, Thomas L., Acta Crystallographica, Section E: Structure Reports Online (2007), 63(8), m2153-m2154.

 

62. "A new high-pressure CaGe2O5 polymorph with 5- and 6-coordinated germanium", Nemeth, Peter; Leinenweber, Kurt; Groy, Thomas L.; Buseck, Peter R., American Mineralogist (2007), 92(2-3), 441-443.

 

63. "1,3-Bis(3,4,5-trimethoxyphenyl)-2,3-epoxypropanone: an anticancer chalcone epoxide", Cuthbertson, Timothy; Groy, Thomas L.; Rose, Seth D., Acta Crystallographica, Section E: Structure Reports Online (2005), 61(12), o4300-o4302.

 

64. "Anhydrous 1-methylimidazolidin-2-one", Caudle, M. Tyler; Tassone, Erica; Groy, Thomas L., Acta Crystallographica, Section E: Structure Reports Online (2005), 61(10), o3269-o3270.

 

65. "High-pressure synthesis and crystal structure of silicon phosphate hydroxide, SiPO4(OH)", Stearns, Linda A.; Groy, Thomas L.; Leinenweber, Kurt, Journal of Solid State Chemistry (2005), 178(9), 2594-2601.

 

66. "Phase Measurement for Accurate Mapping of Chemical Bonds in Acentric Space Groups", Spackman, M. A.; Jiang, B.; Groy, T. L.; He, H.; Whitten, A. E.; Spence, J. C. H., Physical Review Letters (2005), 95(8), 085502/1-085502/4.

 

67. "Ca2SiO3OHF - a high-pressure phase with dense calcium polyhedral packing and tetrahedral silicon", Leinenweber, Kurt; Johnson, Jennifer E.; Groy, Thomas L., American Mineralogist (2005), 90(1), 115-121.

 

68. "Application of a modified Oszlanyi and Sueto ab initio charge-flipping algorithm to experimental data", Wu, J. S.; Spence, J. C. H.; O'Keeffe, M.; Groy, T. L., Acta Crystallographica, Section A: Foundations of Crystallography (2004), A60(4), 326-330.

 

69. "Carbon-Sulfur Bond Cleavage in Bis(N-alkyldithiocarbamato)cadmium(II) Complexes: Heterolytic Desulfurization Coupled to Topochemical Proton Transfer", van Poppel, Laura H.; Groy, Thomas L.; Caudle, M. Tyler, Inorganic Chemistry (2004), 43(10), 3180-3188.

 

70. "EPR and Magnetic Properties of Heteronuclear MnnMg6-n(O2CNEt2)12: Impact of Structural Distortions on Mn(II) in Weak Ligand Fields", Caudle, M. Tyler; Mobley, Charles. K.; Bafaro, Laura M.; LoBrutto, Russell; Yee, Gordon T.; Groy, Thomas L., Inorganic Chemistry (2004), 43(2), 506-514.

 

71. "Crystal structure of protoanthophyllite: A new mineral from the Takase ultramafic complex, Japan", Konishi, Hiromi; Groy, Thomas L.; Dodony, Istvan; Miyawaki, Ritsuro; Matsubara, Satoshi; Buseck, Peter R., American Mineralogist (2003), 88(11-12, Pt. 1), 1718-1723.

 

72. "Synthesis and Characterization of Zirconogermanates", Plevert, Jacques; Sanchez-Smith, Rebeca; Gentz, Travis M.; Li, Hailian; Groy, Thomas L.; Yaghi, Omar M.; O'Keeffe, Michael, Inorganic Chemistry (2003), 42(19), 5954-5959.

 

73. "Molecular structure and reactivity of monoalkyldithiocarbamato cadmium (II) compounds", van Poppel, Laura; Groy, Thomas L.; Caudle, M. Tyler, Abstracts of Papers, 226th ACS National Meeting, New York, NY, United States, September 7-11, 2003 (2003), INOR-670.

 

74. "Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters", Plevert, Jacques; Gentz, Travis M.; Groy, Thomas L.; O'Keeffe, Michael; Yaghi, Omar M., Chemistry of Materials (2003), 15(3), 714-718.

 

75. "Crystal structure of tin tetrabromide dioxane, SnBr4.(C4H8O2), a one dimensional polymer of Sn(IV)", Bauer, M.; Kouvetakis, J.; Groy, T. L., Zeitschrift fuer Kristallographie - New Crystal Structures (2002), 217(3), 421-422.

 

76. "trans-Tetrabromobis(dimethylamine)tin", Ritter, Cole, III; Groy, Thomas L.; Kouvetakis, John, Acta Crystallographica, Section E: Structure Reports Online (2002), 58(11), m684-m685.

 

77. "1,4,5,8-Tetramethoxyanthracene", Springer, J. W.; Moore, T. A.; Moore, A. L.; Gust, Devens; Groy, Thomas L., Acta Crystallographica, Section E: Structure Reports Online (2002), 58(10), o1145-o1146.

 

78. "Metal Ion Scrambling in Hexanuclear M6(Et2NCO2)12 Complexes (M = Co, Mg). Synthesis, Solid State Structure, and Solution Dynamics of Heteronuclear ConMg6-n(Et2NCO2)12 Complexes", Caudle, M. Tyler; Benedict, Jason B.; Mobley, Charles K.; Straessler, Nicholas A.; Groy, Thomas L., Inorganic Chemistry (2002), 41(12), 3183-3190.

 

79. "Mg(II) ion dependence on the amide proton exchange rates of biotin", Sanchez, Elizabeth R.; Groy, Thomas L.; Caudle, M. Tyler, Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002 (2002), INOR-407.

 

80. "Synthesis, Structure, and Preparative Transamination of Tetrazinc Carbamato Complexes Having the Basic Zinc Carboxylate Structure", McCowan, C. Shawn; Groy, Thomas L.; Caudle, M. Tyler, Inorganic Chemistry (2002), 41(5), 1120-1127.

 

81. "Interaction of Biotin with Mg-O Bonds: Bifunctional Binding and Recognition of Biotin and Related Ligands by the Mg(15-crown-5)2+ Unit", Sanchez, Elizabeth R.; Gessel, Mary C.; Groy, Thomas L.; Caudle, M. Tyler, Journal of the American Chemical Society (2002), 124(9), 1933-1940.

 

82. "Recognition and cleavage at the DNA major groove", Skibo, E. B.; Xing, C.; Groy, T., Bioorganic & Medicinal Chemistry (2001), 9(9), 2445-2459.

 

83. "Crystal structure of bis(trimethylamine) dichlorodeuteroalane, [N(CH3)3]2Cl2DAl", Torrison, L.; Groy, T. L.; Kouvetakis, J., Zeitschrift fuer Kristallographie - New Crystal Structures (2001), 216(3), 467-468.

 

84. "20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks", Li, Hailian; Kim, Jaheon; Groy, T. L.; O'Keeffe, M.; Yaghi, O. M., Journal of the American Chemical Society (2001), 123(20), 4867-4868.

 

85. "Synthesis of new azidoalanes with heterocyclic molecular structures", Kouvetakis, J.; McMurran, J.; Steffek, Cory; Groy, T. L.; Hubbard, John L.; Torrison, L., Main Group Metal Chemistry (2001), 24(2), 77-84.

 

86. "Crystal structure and bonding in the high-pressure form of fluorite (CaF2)", Morris, E.; Groy, T.; Leinenweber, K., Journal of Physics and Chemistry of Solids (2001), 62(6), 1117-1122.

 

87. "2,4,6-Tris[2-(trimethylsilyl)ethynyl]-1,3,5-triazene: a novel precursor to C-N two-dimensional structures", Kouvetakis, John; Groy, Thomas L., Acta Crystallographica, Section C: Crystal Structure Communications (2000), C56(11), E533.

 

88. "The centrosymmetric dimer of dichloro(trimethylsilyloxy)aluminium", Kouvetakis, John; Ritter, Cole; Groy, Thomas L., Acta Crystallographica, Section C: Crystal Structure Communications (2000), C56(12), e564.

 

89. "Synthesis and Structures of Heterocyclic Azidogallanes [(CH3)ClGaN3]4 and [(CH3)BrGaN3]3 en Route to [(CH3)HGaN3]x: An Inorganic Precursor to GaN", Kouvetakis, J.; McMurran, J.; Steffek, Cory; Groy, T. L.; Hubbard, John L., Inorganic Chemistry (2000), 39(17), 3805-3809.

 

90. "X-ray crystal structure of the cytotoxic planar Ni(II) complex of 4N-dimethyl-2-acetylpyridine thiosemicarbazone", Murugkar, Anupa; Bendre, Ratnamala; Padhye, Subhash; Groy, Thomas, Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry (1999), 38A(10), 981-984.

 

91. "Design and synthesis of metal-carboxylate frameworks with permanent microporosity", Eddaoudi, Mohamed; Li, Hailian; Reineke, Theresa; Fehr, Michael; Kelley, Douglas; Groy, Thomas L.; Yaghi, O. M., Topics in Catalysis (1999), 9(1,2), 105-111.

 

92. "Crystal structure of kanemite, NaHSi2O5·3H2O, from the Aris phonolite, Namibia", Garvie, Laurence A. J.; Devouard, Bertrand; Groy, Thomas L.; Camara, Fernando; Buseck, Peter R., American Mineralogist (1999), 84(7-8), 1170-1175.

 

93. "Designing ordered arrays of lewis acid sites in microporous metal-organic materials", Yaghi, O. M.; Li, Hailian; Eddauodi, Mohamed; Groy, T. L., Book of Abstracts, 217th ACS National Meeting, Anaheim, Calif., March 21-25 (1999), INOR-007.

 

94. "Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids", Yaghi, Omar M.; Li, Hailian; Davis, Charles; Richardson, David; Groy, Thomas L., Accounts of Chemical Research (1998), 31(8), 474-484.

 

95. "Establishing Microporosity in Open Metal-Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)", Li, Hailian; Eddaoudi, Mohamed; Groy, Thomas L.; Yaghi, O. M., Journal of the American Chemical Society (1998), 120(33), 8571-8572.

 

96. "Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-Benzenedicarboxylate)", Li, Hailian; Davis, Charles E.; Groy, Thomas L.; Kelley, Douglas G.; Yaghi, O. M., Journal of the American Chemical Society (1998), 120(9), 2186-2187.

 

97. "Porous hydrogen-bonded networks.", Laine, Aaron M.; Yaghi, Omar M.; Groy, Thomas L., Book of Abstracts, 215th ACS National Meeting, Dallas, March 29-April 2 (1998), INOR-355.

 

98. "Synthesis and characterization of molybdenum(II) and molybdenum(V) monothiocarbamate complexes. Crystal and molecular structures of tetrakis(isopropylmonothiocarbamato)dimolybdenum(II) and oxobis[di(oxoisopropylmonothiocarbamato)molybdenum(V)]", Calcaterra, Anthony D.; Kimble, Scott B.; Groy, T. L.; Brown, T. M., Inorganica Chimica Acta (1998), 267(1), 101-107.

 

99. "Crystal structure of 1,2,4,5-benzenetetracarboxylate monohydrate cerium(III)", Yaghi, O. M.; Li, H.; Groy, T. L., Zeitschrift fuer Kristallographie - New Crystal Structures (1997), 212(3), 457-458.

 

100. "Crystal structure of vanadyl monohydrogen phosphate bis(2,2'-dipyridine) monohydrate, C20H19N4O9PV2", Yaghi, O. M.; Li, H.; Groy, T. L., Zeitschrift fuer Kristallographie - New Crystal Structures (1997), 212(3), 455-456.

 

101. "Crystal structure of cyclotetra(1,4-dithiobenzene), C24H16S8", Yaghi, O. M.; Li, H.; Groy, T. L., Zeitschrift fuer Kristallographie - New Crystal Structures (1997), 212(3), 453-454.

 

102. "A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4'-bpy)2.5(H2O)2(ClO4)2·1.5(4,4'-bpy)·2H2O", Yaghi, O. M.; Li, Hailian; Groy, Thomas L., Inorganic Chemistry (1997), 36(20), 4292-4293.

 

103. "Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks", Yaghi, Omar M.; Jernigan, Ryan; Li, Hailian; Davis, Charles E.; Groy, Thomas L., Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1997), (14), 2383-2384.

 

104. "Highly-selective binding of molecules and ions in tailored porous coordination solids.", Yaghi, O. M.; Li, Hailian; Davis, C. E.; Groy, T. L., Book of Abstracts, 214th ACS National Meeting, Las Vegas, NV, September 7-11 (1997), I&EC-037.

 

105. "Decorating the channels of porous coordination solids.", Yaghi, O. M.; Li, Hailian; Davis, C. E.; Groy, T. L., Book of Abstracts, 213th ACS National Meeting, San Francisco, April 13-17 (1997), INOR-448.

 

106. "Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid", Yaghi, O. M.; Li, Hailian; Groy, T. L., Journal of the American Chemical Society (1996), 118(38), 9096-9101.

 

107. "Porous metal-organic frameworks.", Yaghi, Omar M.; Li, Hailian; Davis, Charles; Groy, Thomas, Book of Abstracts, 212th ACS National Meeting, Orlando, FL, August 25-29 (1996), INOR-250.

 

108. "Chloro(propionyl-C)[2(1H)-pyridonato-N,O]bis[tris(1-methylethyl)phosphine]iridium(III)", Grotjahn, Douglas B.; Lo, H. C.; Groy, Thomas L., Acta Crystallographica, Section C: Crystal Structure Communications (1996), C52(3), 516-19.

 

109. "Chlorohydrido[2(1H)-pyridonato-N,O]bis[tris(1-methylethyl)phosphine]iridium(III)", Grotjahn, Douglas B.; Lo, Huiyue C.; Groy, Thomas L., Acta Crystallographica, Section C: Crystal Structure Communications (1996), C52(2), 300-2.

 

110. "Synthesis and Characterization of Tetrakis(trihalogermyl)methanes. Molecules Containing Sterically Strained Carbon Centers", Matsunaga, Phillip T.; Kouvetakis, John; Groy, Thomas L., Inorganic Chemistry (1995), 34(21), 5103-4.

 

111. "Formation and Structure of Coordinatively Unsaturated CpIr-Amino Acid Complexes. Kinetic and Thermodynamic Control in Highly Diastereoselective Complexation Reactions", Grotjahn, D. B.; Groy, T. L., Organometallics (1995), 14(8), 3669-82.

 

112. "Preparation of single crystals of coordination solids in silica gels: synthesis and structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4", Yaghi, O. M.; Guangming, Li; Groy, T. L., Journal of Solid State Chemistry (1995), 117(2), 256-60.

 

113. "Novel Synthetic Routes to Carbon Nitride", Todd, M.; Kouvetakis, J.; Groy, T. L.; Chandrasekhar, D.; Smith, David J.; Deal, P. W., Chemistry of Materials (1995), 7(7), 1422-6.

 

114. "Open-framework solids with diamond-like structures prepared from clusters and metal-organic building blocks", Yaghi, Omar M.; Richardson, D. A.; Li, G.; Davis, E.; Groy, T. L., Materials Research Society Symposium Proceedings (1995), 371(Advances in Porous Materials), 15-19.

 

115. "Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C4O42-) molecules, chains and sheets to three-dimensional cage networks", Yaghi, Omar M.; Li, Guangming; Groy, Thomas L., Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1995), (5), 727-32.

 

116. "The Dolastatins. 22. Synthesis Of Boc-Dolaproinyl Dolaphenine and Four Related Chiral Isomers", Pettit, George R.; Barkoczy, Jozsef; Srirangam, Jayaram K.; Singh, Sheo Bux; Herald, Delbert L.; Williams, Michael D.; Kantoci, Darko; Hogan, Fiona; Groy, Thomas L., Journal of Organic Chemistry (1994), 59(11), 2935-8.

 

117. "Formation of Coordinatively Unsaturated Cp*Ir-Amino Acid Complexes and Their Highly Diastereoselective Complexation Reactions", Grotjahn, D. B.; Groy, T. L., Journal of the American Chemical Society (1994), 116(15), 6969-70.

 

118. "Directed Transformation of Molecules to Solids: Synthesis of a Microporous Sulfide from Molecular Germanium Sulfide Cages", Yaghi, O. M.; Sun, Z.; Richardson, D. A.; Groy, T. L., Journal of the American Chemical Society (1994), 116(2), 807-8.

 

119. "Structures of two spiro[cyclopropane-1,3'-indoline]-cis,syn-1,3-dimethyluracil cyclobutane photodimers", Groy, Thomas L.; Kim, Sang Tae; Rose, Seth D., Acta Crystallographica, Section C: Crystal Structure Communications (1991), C47(9), 1898-902.

 

120. "Long zirconium-sulfur bonds in the structure of the stereochemically nonrigid complex, bis(η5-cyclopentadienyl)(N,N-dimethyldithiocarbamato)phenoxyzirconium(IV)", Femec, Douglas A.; Groy, Thomas L.; Fay, Robert C., Acta Crystallographica, Section C: Crystal Structure Communications (1991), C47(9), 1811-14.

 

121. "Structure of 5-[2-(3-indolyl)ethyl]-1,3-dimethyluracil 1,3-dimethyluracil cis,syn-cyclobutane photodimer", Groy, Thomas L.; Kim, Sang Tae; Rose, Seth D., Acta Crystallographica, Section C: Crystal Structure Communications (1991), C47(6), 1287-90.

 

122. "Structure of a bis(osmate ester) produced by addition of osmium tetroxide to diethyl 3,4-furandicarboxylate", Groy, Thomas L.; Hartman, Rosemarie F.; Rose, Seth D., Acta Crystallographica, Section C: Crystal Structure Communications (1991), C47(2), 273-5.

 

123. "Sterols of marine invertebrates.  63.  Isolation and structure elucidation of sutinasterol, the major sterol of the marine sponge Xestospongia sp", Kerr, Russell G.; Kerr, Sutinah L.; Pettit, George R.; Herald, Delbert L.; Groy, Thomas L.; Djerassi, Carl, Journal of Organic Chemistry (1991), 56(1), 58-62.

 

124. "Splitting of high-temperature x-ray diffraction profiles during the lead monoxide tetragonal orthorhombic phase transformation", Schoonover, J. R.; Groy, T. L.; Lin, S. H., Journal of Solid State Chemistry (1989), 83(1), 207-13.

 

125. "Structural studies of cobalt/chromium multilayered thin films", Stearns, M. B.; Lee, C. H.; Groy, T. L., Physical Review B: Condensed Matter and Materials Physics (1989), 40(12), 8256-69.

 

126. "A theoretical treatment of high-energy electron scattering by clusters and time-resolved x-ray diffraction from reacting solids", Groy, Thomas Lee, No Corporate Source data available (1982), 309 pp..

 

127. "A theoretical study of the application of time-resolved x-ray scattering to solid state reaction kinetics", Groy, Thomas L.; Lin, Sheng H.; Porter, Spencer K.; Von Dreele, Robert B.; Eyring, LeRoy, Fenzi Kexue Xuebao (1981-1982) (1982), 2(4), 93-105.

 

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